Topic: Ions

1:19 understand how to deduce the electronic configurations of the first 20 elements from their positions in the Periodic Table

Electrons are found in a series of shells (or energy levels) around the nucleus of an atom.

Each energy level can only hold a certain number of electrons. Low energy levels are always filled up first.

Rules for working out the arrangement (configuration) of electrons:

Example – chlorine (Cl)

1) Use the periodic table to look up the atomic number. Chlorine’s atomic number (number of protons) is 17.

2) Remember the number of protons = number of electrons. Therefore chlorine has 17 electrons.

3) Arrange the electrons in levels (shells):

  • 1st shell can hold a maximum of 2
  • 2nd can hold a maximum of 8
  • 3rd can also hold 8

Therefore the electron arrangement for chlorine (17 electrons in total) will be written as 2,8,7

4) Check to make sure that the electrons add up to the right number

The electron arrangement can also be draw in a diagram.

Electron arrangement for the first 20 elements:

1:25 write word equations and balanced chemical equations (including state symbols): for reactions studied in this specification and for unfamiliar reactions where suitable information is provided

Example:

Sodium (Na) reacts with water (H2O) to produce a solution of sodium hydroxide (NaOH) and hydrogen gas (H2).

Word equation:

     sodium + water –> sodium hydroxide + hydrogen

Writing the chemical equation

A chemical equation represents what happens in terms of atoms in a chemical reaction.

Step 1: To write a chemical equation we need to know the chemical formulae of the substances.

     Na + H2O –> NaOH + H2

Step 2: The next step is to balance the equation: write a large number before each compound so the number of atoms of each element on the left hand side (reactants) matches the number on the right (products). This large number is the amount of each compound or element.

During this balancing stage the actual formulas for each compound must not be changed. Only the number of each compound changes.

     2Na + 2H2O –> 2NaOH + H2

If asked for an equation, the chemical equation must be given.

 

State symbols are used to show what physical state the reactants and products are in.

State symbolsPhysical state
(s)Solid
(l)Liquid
(g)Gas
(aq)Aqueous solution (dissolved in water)

Example:

A solid piece of sodium (Na) reacts with water (H2O) to produce a solution of sodium hydroxide (NaOH) and hydrogen gas (H2).

     2Na(s) + 2H2O(l) –> 2NaOH(aq) + H2(g)

1:38 know the charges of these ions: metals in Groups 1, 2 and 3, non-metals in Groups 5, 6 and 7, Ag⁺, Cu²⁺, Fe²⁺, Fe³⁺, Pb²⁺, Zn²⁺, hydrogen (H⁺), hydroxide (OH⁻), ammonium (NH₄⁺), carbonate (CO₃²⁻), nitrate (NO₃⁻), sulfate (SO₄²⁻)

Name of IonFormulaCharge
SulfateSO42--2
CarbonateCO32--2
NitrateNO3--1
HydroxideOH--1
AmmoniumNH4++1
Silver ionAg++1
Zinc ionZn2++2

1:39 write formulae for compounds formed between the ions listed in 1:38

Writing the electron configuration of an atom allows you to work out the electron configuration of the ion and therefore the charge on the ion.

 

Examples:

Atom = Mg

Electron configuration = 2,8,2

remove the two electrons from the outer shell to achieve the same electron configuration as the nearest noble gas, Neon (Ne 2,8)

Ion = Mg2+ 

[2,8]2+

 

Atom = O

Electron configuration = 2,6

add two electrons to the outer shell to achieve the same electron configuration as the nearest noble gas, Neon (Ne 2,8)

Ion = O2-  [2,8]2-

 

1:40 draw dot-and-cross diagrams to show the formation of ionic compounds by electron transfer, limited to combinations of elements from Groups 1, 2, 3 and 5, 6, 7 only outer electrons need be shown

Sodium chloride, NaCl

 
  
Magnesium chloride, MgCl2

 
Potassium oxide, K2O

 

Calcium oxide, CaO

 
Aluminium oxide, Al2O3
 
 
Magnesium nitride, Mg3N2

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Section 1: Principles of chemistry

      a) States of matter

      b) Atoms

      c) Atomic structure

     d) Relative formula masses and molar volumes of gases

     e) Chemical formulae and chemical equations

     f) Ionic compounds

     g) Covalent substances

     h) Metallic crystals

     i) Electrolysis

 Section 2: Chemistry of the elements

     a) The Periodic Table

     b) Group 1 elements: lithium, sodium and potassium

     c) Group 7 elements: chlorine, bromine and iodine

     d) Oxygen and oxides

     e) Hydrogen and water

     f) Reactivity series

     g) Tests for ions and gases

Section 3: Organic chemistry

     a) Introduction

     b) Alkanes

     c) Alkenes

     d) Ethanol

Section 4: Physical chemistry

     a) Acids, alkalis and salts

     b) Energetics

     c) Rates of reaction

     d) Equilibria

Section 5: Chemistry in industry

     a) Extraction and uses of metals

     b) Crude oil

     c) Synthetic polymers

     d) The industrial manufacture of chemicals