3:02 describe simple calorimetry experiments for reactions such as combustion, displacement, dissolving and neutralisation
Calorimetry allows for the measurement of the amount of energy transferred in a chemical reaction to be calculated.
EXPERIMENT1: Displacement, dissolving and neutralisation reactions
Example: magnesium displacing copper from copper(II) sulfate
- 50 cm3 of copper(II) sulfate is measured and transferred into a polystyrene cup.
- The initial temperature of the copper sulfate solution is measured and recorded.
- Magnesium is added and the maximum temperature is measured and recorded.
- The temperature rise is then calculated. For example:
|Initial temp. of solution (oC)||Maximium temp. of solution (oC)||Temperature rise (oC)|
Note: mass of 50 cm3 of solution is 50 g
The cup used is polystyrene because:
polystyrene is an insulator which reduces heats loss
EXPERIMENT2: Combustion reactions
To measure the amount of energy produced when a fuel is burnt, the fuel is burnt and the flame is used to heat up some water in a copper container
Example: ethanol is burnt in a small spirit burner
- The initial mass of the ethanol and spirit burner is measured and recorded.
- 100cm3 of water is transferred into a copper container and the initial temperature is measured and recorded.
- The burner is placed under of copper container and then lit.
- The water is stirred constantly with the thermometer until the temperature rises by, say, 30 oC
- The flame is extinguished and the maximum temperature of the water is measured and recorded.
- The burner and the remaining ethanol is reweighed. For example:
|Mass of water (g)||Initial temp of water (oC)||Maximum temp of water (oC)||Temperature rise (oC)||Initial mass of spirit burner + ethanol (g)||Final mass of spirit burner + ethanol (g)||Mass of ethanol burnt (g)|
The amount of energy produced per gram of ethanol burnt can also be calculated: